Introduction - If you have any usage issues, please Google them yourself
For a simple two step converter, a psudo-random sequence can be injected into the sub-ADC and correlated with the digital output to determine radix errors. See Li and Moon, TCAS II, Sept 2003 or Keane, TCAS I, Jan 2005 for more info.
Below is a Matlab script which will extract the radix error from a two stage ADC with PN correlation techniques: